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What is the difference between NiCad, NiMH and Lithium Ion batteries?

Batteries in portable consumer devices such as a laptop, camcorder, cellular phone, etc., are typically made using either Nickel Cadmium (NiCad), Nickel Metal Hydride (NiMH) or Lithium Ion (Li-Ion) battery cell chemistry. Each type of rechargeable battery chemistry has its own unique characteristics:

NiCad and NiMH:

The main difference between the two is that NiMH battery (the newer technology of the two) offers higher energy density than NiCads. In other words, the capacity of a NiMH is approximately twice the capacity of its NiCad counterpart. What this means is for you is increased run-time from the battery with no additional bulk or weight. NiMH also offers another major advantage: NiCad batteries tend to suffer from what is called the “memory effect”. NiMH batteries are less prone to develop this problem and thus require less maintenance and conditioning. NiMH batteries are also environmentally friendlier than NiCad batteries since they do not contain heavy metals (which present serious landfill problems). Note: Not all devices can accept both NiCad or NiMH batteries.

Lithium Ion

Lithium-Ion (Li-Ion) has become the new standard for portable power in consumer devices. Li-Ion batteries produce the same energy as NiMH battery but weighs approximately 20%35% less. This is can make a noticeable difference in devices such as cellular phones, camcorders, multimedia device, GPS device or notebook computers where the battery makes up a significant portion of the total weight. Another reason Li-Ion batteries have become so popular is that they do not suffer from the “memory effect” at all. They are also environmentally friendly because they don’t contain toxic materials such as Cadmium or Mercury.

Cells sold today as polymer batteries have a different design from the older lithium-ion cells. Unlike lithium-ion cylindrical, or prismatic cells, which have a rigid metal case, polymer cells have a flexible, foil-type (polymer laminate) case, but they still contain organic solvent. The main difference between commercial polymer and lithium-ion cells is that in the latter the rigid case presses the electrodes and the separator onto each other, whereas in polymer cells this external pressure is not required because the electrode sheets and the separator sheets are laminated onto each other.

Since no metal battery cell casing is needed, the battery can be lighter and it can be specifically shaped to fit the device it will power. Because of the denser packaging without intercell spacing between cylindrical cells and the lack of metal casing, the energy density of Li-poly batteries is over 20% higher than that of a classical Li-ion battery and approximately three times better than NiCd and NiMH batteries.

The voltage of a Li-poly cell varies from about 2.7 V (discharged) to about 4.23 V (fully charged), and Li-poly cells have to be protected from overcharge by limiting the applied voltage to no more than 4.235 V per cell used in a series combination. Overcharging a Li-poly battery will likely result in explosion and/or fire. During discharge on load, the load has to be removed as soon as the voltage drops below approximately 3.0 V per cell (used in a series combination), or else the battery will subsequently no longer accept a full charge and may experience problems holding voltage under load.

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The Do’s and Don’ts of Battery Use

1) Battery Do’s:

Fully charge/discharge battery up to 4 cycles before achieving full capacity of a new battery

Fully discharge and then fully charge the battery every two to three weeks for battery conditions.

Run the device under the battery’s power until it shuts down or until you get a low battery warning. Then recharge the battery as instructed in the user’s manual.

Remove from the device and stored in a cool, dry, clean place if the battery will not be in use for a month or longer,

Recharge the battery after a storage period

Ensure maximum performance of the battery by optimizing the device’s power management features. Refer to the manual for further instructions.

2) Battery Don’ts:

Do not short-circuit. A short-circuit may cause severe damage to the battery.

Do not drop, hit or otherwise abuse the battery as this may result in the exposure of the cell contents, which are corrosive.

Do not expose the battery to moisture or rain.

Keep battery away from fire or other sources of extreme heat. Do not incinerate. Exposure of battery to extreme heat may result in an explosion.

My new battery isn’t charging. Is it defective?

Usually NO. New batteries come in a discharged condition and must be fully charged before use. It is recommended that you fully charge and discharge the new battery two to four times to allow it to reach its maximum rated capacity

It is generally recommend an overnight charge (approximately twelve hours). It is normal for a battery to become warm to the touch during charging and discharging.

When charging the battery for the first time, the device may indicate that charging is complete after just 10 or 15 minutes. This is a normal with rechargeable batteries. New batteries are hard for the device to charge; they have never been fully charged and not “broken in.” Sometimes the device’s charger will stop charging a new battery before it is fully charged. If this happens, remove the battery from the device and then reinsert it. The charge cycle should begin again. This may happen several times during the first battery charge. Don’t worry; it’s perfectly normal.

How can I maximize the performance of my battery?

There are several steps you can take to help you get maximum performance from your battery:

Prevent the Memory Effect - Keep the battery healthy by fully charging and then fully discharging it at least once every two to three weeks. Exceptions to the rule are Li-Ion batteries which do not suffer from the memory effect.

Keep the Batteries Clean - It’s a good idea to clean dirty battery contacts with a cotton swab and alcohol. This helps maintain a good connection between the battery and the portable device.

Exercise the Battery - Do not leave the battery dormant for long periods of time. We recommend using the battery at least once every two to three weeks. If a battery has not been used for a long period of time, perform the new battery procedure described above.

Battery Storage - If you don’t plan on using the battery for a month or more, store it in a clean, dry, cool place away from heat and metal objects. NiCad, NiMH and Li-Ion batteries will self-discharge during storage; remember to recharge the batteries before use.

Sealed Lead Acid - (SLA) batteries must be kept at full charge during storage. This is usually achieved by using special trickle chargers. If you do not have a trickle charger, do not attempt to store SLA batteries for more than three months.